Polyacrylamide (PAM), a high-molecular-weight water-soluble polymer, is widely recognized as an efficient flocculant and coagulant aid in pig farm wastewater treatment. Pig farm wastewater is characterized by high concentrations of suspended solids (SS), chemical oxygen demand (COD), biological oxygen demand (BOD), ammonia nitrogen (NH₄⁺-N), total nitrogen (TN), total phosphorus (TP), and organic pollutants such as fecal residues and feed scraps, which pose significant threats to the ecological environment if discharged without proper treatment. PAM exhibits excellent performance in solid-liquid separation, pollutant removal, and sludge dewatering due to its charge neutralization, adsorption bridging, and flocculation aggregation properties, making it an indispensable core reagent in the standard treatment of pig farm wastewater. It not only improves treatment efficiency and effluent quality but also reduces treatment costs and realizes the resource utilization of sludge, providing a reliable technical support for the green and sustainable development of the pig breeding industry.
The application effect of PAM in pig farm wastewater treatment is mainly realized through three core mechanisms, which work together to achieve efficient purification of wastewater:
PAM is widely used in all key links of pig farm wastewater treatment, from pretreatment to advanced treatment and sludge disposal, and its application effect is closely related to the type of PAM, dosage, wastewater quality, and environmental conditions (such as temperature and pH value). The main application scenarios are as follows:
The pretreatment of pig farm wastewater (mainly flushing wastewater from pig houses and biogas slurry) focuses on removing large suspended solids and reducing the pollutant load of subsequent treatment links. PAM is usually used in combination with inorganic coagulants (such as polyaluminum chloride, PAC) to enhance the flocculation effect. After adding PAM, the suspended particles in wastewater quickly aggregate into large flocs, which are then separated by sedimentation tanks, inclined plate sedimentation tanks, or rotary screens. This link can effectively remove 80%-95% of SS, reduce 30%-60% of COD and BOD, and lay a foundation for the subsequent biochemical treatment.
After biochemical treatment (anaerobic, aerobic process), the concentration of pollutants such as COD, BOD, and NH₄⁺-N in pig farm wastewater is significantly reduced, but there are still a small amount of fine suspended solids, colloidal organic matter, and residual TP, which are difficult to meet the strict discharge standards. At this time, adding a small amount of PAM (anionic or non-ionic) can further flocculate and precipitate these residual pollutants, improve the clarity of effluent, and ensure that COD, SS, and TP meet the national or local discharge standards (such as GB 18596-2001 "Pollution Control Standard for Livestock and Poultry Breeding Industry").
A large amount of sludge is generated in the process of pig farm wastewater treatment, which has high moisture content (usually 95%-98%) and large volume, making it difficult to store, transport, and dispose of. PAM (mainly cationic) is used as a sludge dewatering agent to modify the sludge: it can break the stable structure of sludge colloids, release bound water in sludge, and form dense sludge flocs, which can be quickly dewatered by filter presses (plate and frame filter presses, belt filter presses) to reduce the moisture content of sludge to 60%-70% (or even lower). This not only reduces the volume of sludge by more than 70% but also makes the dewatered sludge easy to be composted, incinerated, or landfilled, realizing the reduction and resource utilization of sludge.
The following tables summarize the application parameters, pollutant removal effects, and economic indicators of different types of PAM in pig farm wastewater treatment, based on actual test data and on-site application cases from domestic and foreign research institutions and pig farms. The data can provide a reference for the selection and dosage adjustment of PAM in actual engineering.
| PAM Type | Molecular Weight (million) | Ionic Degree (%) | Dosage (mg/L) | Wastewater pH | SS Removal Rate (%) | COD Removal Rate (%) | TP Removal Rate (%) | Matching Coagulant |
| Cationic PAM | 8-12 | 40-60 | 10-30 | 6.5-8.5 | 85-95 | 35-55 | 70-85 | PAC (200-500 mg/L) |
| Cationic PAM (moderate charge) | 10-14 | 20 | 26-79 | 7.0-8.0 | 90-94 | 40-60 | 75-88 | PAC (300-400 mg/L) |
| Anionic PAM | 12-18 | 20-40 | 15-40 | 7.0-9.0 | 80-90 | 30-50 | 65-80 | PAC (250-500 mg/L) |
| Non-ionic PAM | 10-15 | - | 20-50 | 6.0-8.0 | 75-85 | 25-45 | 60-75 | PFS (200-400 mg/L) |
| PAM Type | Dosage (kg/t Sludge) | Sludge Moisture Content Before Dewatering (%) | Sludge Moisture Content After Dewatering (%) | Sludge Reduction Rate (%) | Dewatering Equipment | Sludge Cake Form |
| Cationic PAM | 1.0-3.0 | 96-98 | 60-70 | 70-75 | Plate and Frame Filter Press | Dense, non-sticky, easy to peel |
| Cationic PAM | 1.5-4.0 | 95-97 | 65-75 | 65-70 | Belt Filter Press | Loose, uniform, no dripping |
| Cationic PAM (high ionic degree) | 0.8-2.5 | 97-98 | 58-68 | 72-78 | Diaphragm Filter Press | Compact, high strength, low moisture content |
| Temperature Range (℃) | PAM Type | PAM Dosage (mg/L) | Matching PAC Dosage (g/L) | Optimal pH | TN Removal Rate (%) | TP Removal Rate (%) | Flocculation Cost (Yuan/t Wastewater) |
| Low (2-9) | Cationic PAM | 96.91 | 7.24 | 6.41 | ≥82.0 | ≥82.58 | Reduced by 6.57 |
| Medium (11-17) | Cationic PAM | 77.61 | 5.12 | 7.22 | ≥86.81 | ≥85.0 | Reduced by 14.33 |
| High (29-36) | Cationic PAM | 21.99 | 2.93 | 8.38 | ≥84.0 | ≥83.0 | Reduced by 20.88 |
| Farm Location | PAM Dosage (mg/L) | COD Removal Rate (%) | BOD₅ Removal Rate (%) | TSS Removal Rate (%) | TP Removal Rate (%) | Pig Scale (per farm) |
| Modena, Italy | 100-120 | 84.33 | 84.80 | 95.02 | 89.12 | 4000-8000 |
| Barcelona, Spain | 100-120 | 62.98 | 63.33 | 83.56 | 86.31 | 4000-8000 |
| Murcia, Spain | 100-120 | 73.30 | 87.19 | 89.48 | 71.76 | 4000-8000 |
| Goshen, USA | 10-30 | 69.00 | 71.00 | 93.00 | 72.00 | 4000-8000 |
Polyacrylamide, with its efficient flocculation performance and flexible application characteristics, plays an irreplaceable role in pig farm wastewater treatment. It can effectively solve the problems of high pollutant concentration, difficult solid-liquid separation, and difficult sludge disposal in pig farm wastewater, help pig farms achieve standard discharge of wastewater and resource utilization of sludge, and reduce environmental pollution risks. By selecting the appropriate type of PAM, controlling the reasonable dosage, and adopting scientific application methods, the treatment efficiency can be maximized, the treatment cost can be reduced, and the sustainable development of the pig breeding industry can be promoted. With the continuous improvement of environmental protection standards, the application of PAM in pig farm wastewater treatment will be more refined and efficient, and it will also provide more technical support for the green transformation of the livestock and poultry breeding industry.